| Rank | AG | Name | Time |
|---|---|---|---|
| 🥇 | 🥇 | 🇵🇹João Leitão, 🇵🇹Tânia Cruz | 1:01:12 |
| 🥈 | 🥇 | 🇪🇸David Queiroz, 🇵🇹Ana Carvalho | 1:01:56+0:44 |
| 🥉 | 🥇 | 🇫🇷Sandra Chetaneau, 🇫🇷Brice Ablasou | 1:02:09+0:13 |
| #4 | 🥈 | 🇪🇸Ekain Nogueira, 🇪🇸Ania Arregi Celayeta | 1:02:24+0:15 |
| #5 | 🥉 | 🇪🇸Irati Beorlegi, 🇪🇸Gorka Zubizarreta Calvo | 1:02:36+0:12 |
| #6 | #4 | 🇪🇸Sara Neves, 🇪🇸António Ferreira | 1:03:00+0:24 |
| #7 | 🥈 | 🇪🇸Kyle Rimmer Greaves, 🇪🇸Amaia Malaina Celada | 1:03:21+0:21 |
| #8 | 🥉 | 🇪🇸Mikel Saez De Lafuente Rubio, 🇪🇸Idoia Olabarrieta Arranz | 1:04:13+0:52 |
| #9 | #5 | 🇪🇸Davide Oneda, 🇪🇸Alba Moreno Miralles | 1:04:17+0:04 |
| #10 | #4 | 🇪🇸Rossana Spagnuolo, 🇪🇸Francisco Javier Lozano Flores Lozano | 1:04:34+0:17 |
| #11 | 🥈 | 🇪🇸Sergio Monteagudo, 🇪🇸Maite Salgado | 1:04:53+0:19 |
| #12 | #6 | 🇪🇸Jon Imanol Gaspar Pintado, 🇪🇸Ainize Lizarralde Ugalde | 1:04:59+0:06 |
| #13 | #5 | 🇪🇸Oscar Cao Alvarez, 🇪🇸Sara Virginia Isidro Read | 1:05:04+0:05 |
| #15 | #7 | 🇪🇸Maitane Lopez Gonzalez, 🇪🇸Aritz Iginitz Oyarzabal | 1:05:33+0:29 |
| #16 | #7 | 🇫🇷Ghani Khelif, 🇫🇷Manon Antunes | 1:05:51+0:18 |
| #17 | #8 | 🇪🇸Cristina Obrador Ramos, 🇪🇸Bernardo José Bustos Martínez | 1:06:04+0:13 |
| #18 | #9 | 🇪🇸Marta Maria Real Amengual, 🇪🇸Giacomo Colombo | 1:06:21+0:17 |
| #19 | #8 | 🇪🇸Diana Lopez Centeno, 🇪🇸Haritz Diaz Mugica | 1:06:42+0:21 |
| #20 | #9 | 🇪🇸Uxue Sordo Nespral, 🇪🇸Joel Vázquez Medina | 1:06:46+0:04 |
| #21 | #10 | 🇪🇸Almudena Carvajal Noriega, 🇪🇸Iban Barrutia Uralde | 1:06:48+0:02 |
| #22 | #11 | 🇪🇸Ricardo Venegas González, 🇪🇸Rosa Martinez Martinez | 1:06:59+0:11 |
| #23 | #10 | 🇪🇸Aitor Gonzalez Lopez, 🇪🇸Andrea Azkune | 1:07:01+0:02 |
| #24 | #12 | 🇪🇸Miriam De Los Mozos Santos, 🇪🇸Luis Francisco Sanz Daz | 1:07:10+0:09 |
| #25 | 🥉 | 🇪🇸Ruben Coto Hernandez, 🇪🇸Gema Valle Murias Moya | 1:07:10 |
| #26 | #13 | 🇪🇸Cristina Mut Cerón, 🇪🇸Álvaro Alonso Coll | 1:07:26+0:16 |
| #27 | #14 | 🇺🇸Mikhail Skurikhin, 🇷🇺Irina Zakharova | 1:07:29+0:03 |
| #28 | #15 | 🇵🇹Telmo Pinho, 🇵🇹Rita Rebelo | 1:07:36+0:07 |
| #29 | #11 | 🇪🇸Gregorio Rodríguez Márquez, 🇪🇸Uxue Irigoyen Bravo | 1:07:48+0:12 |
| #30 | #12 | 🇪🇸Natalia Pinilla, 🇪🇸Adrián Benito Toledo | 1:07:53+0:05 |
| #31 | #16 | 🇪🇸Alvaro Gomez San Emeterio, 🇪🇸Lucia Martinez Martinez | 1:08:17+0:24 |
| #32 | #17 | 🇵🇹Bruno Ramos, 🇵🇹Júlia Nunes | 1:08:35+0:18 |
| #33 | #13 | 🇪🇸Javier Giner Tobias, 🇪🇸Andrea Molina Giménez | 1:08:50+0:15 |
| #34 | #14 | 🇪🇸Mathilde Delorme, 🇪🇸Ricard Maudsley | 1:08:59+0:09 |
| #36 | #4 | 🇪🇸Luis Gorospe Elizondo, 🇪🇸Itziar Urdapilleta Irazu | 1:09:09+0:10 |
| #35 | #15 | 🇫🇷Benjamin Cloarec, 🇫🇷Camille Cayot | 1:09:09 |
| #37 | 🥇 | 🇪🇸Maria Núñez Caloto, 🇪🇸Juan Jesús Cubillo Rodríguez | 1:09:21+0:12 |
| #38 | #18 | 🇪🇸Alejandra Martinez, 🇪🇸Arkaitz Abad | 1:09:25+0:04 |
| #39 | #5 | 🇪🇸Sanna Hassanaine, 🇫🇷Imanol Rodriguez Municio | 1:09:30+0:05 |
| #40 | #6 | 🇪🇸David Madina, 🇪🇸Veronica Sanchez Benitez | 1:09:38+0:08 |
| #41 | #19 | 🇪🇸Miguel Tomas Riera, 🇪🇸Elisabet Teis Ilari | 1:09:40+0:02 |
| #42 | #16 | 🇪🇸June Ibarguen Martiarena, 🇪🇸Mikel Zurutuza Tovar | 1:09:45+0:05 |
| #43 | #17 | 🇪🇸Diego Roces Surez, 🇪🇸Jennifer Carla Fernández Viña | 1:09:56+0:11 |
| #44 | #20 | 🇪🇸Mamen Cantero Boy, 🇪🇸Marcos Falcon Falcon | 1:10:07+0:11 |
| #45 | #21 | 🇪🇸Diego Fernandez Requejo, 🇪🇸Sara Villa Gonzalez | 1:10:08+0:01 |
| #46 | #18 | 🇪🇸Eider Cantero, 🇪🇸Mikel Alonso Reta | 1:10:16+0:08 |
| #47 | #7 | 🇪🇸Javier García Hernandez, 🇪🇸Cristina Dominguez Blasco | 1:10:17+0:01 |
| #48 | #22 | 🇪🇸Jero Bonzom Bermejo, 🇪🇸Miriam Rodriguez Ibarra | 1:10:18+0:01 |
| #49 | #23 | 🇲🇽Rodrigo Ramirez, 🇪🇸Maitena Masip | 1:10:24+0:06 |
| #50 | #8 | 🇪🇸Idoia Eceiza, 🇪🇸Imanol Gorrotxategi Sangroniz | 1:10:34+0:10 |
| #51 | #19 | 🇪🇸Estanis Carpio, 🇪🇸Carla Carpio | 1:10:48+0:14 |