| Rank | AG | Name | Time |
|---|---|---|---|
| 🥇 | 🥇 | 🇵🇹David Maia, 🇪🇸Sara Pinto | 58:57 |
| 🥈 | 🥇 | 🇵🇹Daniela Couto, 🇵🇹Daniel Sarabanda | 59:51+0:54 |
| 🥉 | 🥈 | 🇩🇪Clemens Reinhardt, 🇩🇪Eva Janzen | 1:00:16+0:25 |
| #4 | 🥉 | 🇪🇸Anna Orozco Torres, 🇪🇸Marc Orozco Torres | 1:01:10+0:54 |
| #5 | 🥇 | 🇬🇧Stuart Tilley, 🇬🇧Rebecca Mason | 1:01:18+0:08 |
| #6 | 🥈 | 🇵🇹Ricardo Ribeiro, 🇵🇹Ana Isabel Coelho | 1:01:22+0:04 |
| #7 | #4 | 🇪🇸Antonio Chillaron Cano, 🇪🇸Cristina Manteiga | 1:02:30+1:08 |
| #8 | #5 | 🇪🇸Samuel Viera Tolosa, 🇪🇸Yadira Pérez Jimenez | 1:03:07+0:37 |
| #9 | 🥈 | 🇵🇹Tiago Lousa, 🇵🇹Marta Caetano | 1:03:34+0:27 |
| #10 | 🥉 | 🇪🇸Jose Antonio Martínez Montalvo, 🇪🇸Alba Pavia Díaz | 1:03:41+0:07 |
| #11 | #4 | 🇪🇸Davide Oneda, 🇪🇸Alba Moreno | 1:04:12+0:31 |
| #12 | #6 | 🇪🇸Sergio Turull Serratosa, 🇪🇸Ana Turull Serratosa | 1:05:02+0:50 |
| #13 | #5 | 🇪🇸Pedro Silva, 🇵🇹Heloísa Braga | 1:05:28+0:26 |
| #14 | #6 | 🇫🇷Mathieu Bertrand, 🇫🇷Chloe Boutchnei | 1:05:50+0:22 |
| #15 | #7 | 🇪🇸Marta Momplet Socies, 🇪🇸Adrià Parra Moya | 1:05:58+0:08 |
| #16 | #7 | 🇮🇪Kieron Keenan, 🇮🇪Emma Coyne | 1:06:02+0:04 |
| #17 | #8 | 🇪🇸Javier Rodriguez Marquez, 🇪🇸Susana Delgado Padilla | 1:06:15+0:13 |
| #18 | 🥉 | 🇪🇸Cristobalina Martin Moreno, 🇪🇸Juan Santiago Marquez | 1:06:27+0:12 |
| #19 | #4 | 🇪🇸Oihane Salcedo González, 🇪🇸Yagoba Urkijo Ramón | 1:06:30+0:03 |
| #20 | #5 | 🇪🇸Arantxa Prado Santiago, 🇪🇸Rubén Fernández Martínez | 1:06:42+0:12 |
| #21 | #8 | 🇵🇹Cláudia Brochado, 🇵🇹Jorge Ribeiro | 1:06:44+0:02 |
| #22 | #9 | 🇪🇸Fernando Carrasco, 🇪🇸Maria Gonzalez Reina | 1:06:45+0:01 |
| #23 | #6 | 🇬🇧Nathan Drinkall, 🇪🇸Nicola Drinkall | 1:06:48+0:03 |
| #24 | #9 | 🇪🇸Emma Vico Iruela, 🇪🇸Fernando Belmonte Rios | 1:07:38+0:50 |
| #25 | #10 | 🇳🇱Max Niessen, 🇳🇱Carmen Kuijer | 1:07:50+0:12 |
| #26 | #10 | 🇧🇺Blaga Veselinova Beletsova, 🇪🇸Iván Fernández Colón | 1:08:00+0:10 |
| #27 | #7 | 🇪🇸Jose Luis Suarez Diaz, 🇪🇸Maria Nuñez Caloto | 1:08:08+0:08 |
| #28 | #11 | 🇪🇸Javier Sanguino Garcia, 🇪🇸Míriam De Frutos Salamanca | 1:08:11+0:03 |
| #29 | #12 | 🇪🇸Lucía Pérez Vega, 🇪🇸Adán Pérez Vega | 1:08:17+0:06 |
| #30 | #11 | 🇪🇸Cristina Obrador Ramos, 🇪🇸Bernardo José Bustos Martínez | 1:08:36+0:19 |
| #31 | #12 | 🇩🇪Paul Zschunke, 🇪🇸Gabi Moeller | 1:09:10+0:34 |
| #32 | #13 | 🇪🇸Adrian Cañas Ortiz, 🇪🇸Ornela Canuti Gaudio | 1:09:40+0:30 |
| #33 | #14 | 🇩🇪Stefanie Roos, 🇩🇪Bjoern Roos | 1:09:54+0:14 |
| #34 | #8 | 🇪🇸Isabel Cruceira Muñoz, 🇪🇸Ángel García Mateo | 1:10:04+0:10 |
| #35 | 🥇 | 🇬🇧Sam Bilbie, 🇬🇧Simon Bilbie | 1:10:05+0:01 |
| #36 | #13 | 🇪🇸Daniel Ruiz Marin, 🇪🇸Sofia Fierros Daza | 1:10:10+0:05 |
| #37 | #14 | 🇪🇸Ainize Lizarralde Ugalde, 🇪🇸Xabier Muñoz Beldarrain | 1:10:14+0:04 |
| #38 | #15 | 🇫🇷Halim Ennadifi, 🇩🇪Bente Aileen Frede | 1:11:03+0:49 |
| #39 | #16 | 🇪🇸Jose Monterroso, 🇪🇸Ester Pedrosa Dorado | 1:11:30+0:27 |
| #40 | #9 | 🇪🇸Jose Julián Rueda Osuna, 🇪🇸Esther Jimenez Palomera | 1:11:47+0:17 |
| #41 | #17 | 🇪🇸Eva Serrano Gil, 🇪🇸Ismael Soria Serrano | 1:11:57+0:10 |
| #42 | #18 | 🇪🇸David González Prieto, 🇪🇸Jessica Sanchez Lopez | 1:12:05+0:08 |
| #43 | #10 | 🇪🇸David Martin Caballero, 🇪🇸María Jose Fernandes De Barros | 1:12:08+0:03 |
| #44 | #19 | 🇪🇸Eva Prieto Hernandez, 🇪🇸Rodrigo Martínez Navarro | 1:12:32+0:24 |
| #45 | #11 | 🇬🇧Brian Rutter, 🇬🇧Faye Rabson | 1:13:10+0:38 |
| #46 | #20 | 🇪🇸Kike Vijande Quintana, 🇪🇸Isle Martinez | 1:13:14+0:04 |
| #47 | #15 | 🇬🇧Chris Brown, 🇬🇧Leah Surkitt | 1:13:19+0:05 |
| #48 | #16 | 🇪🇸Victoria Bernabéu Balibrea, 🇪🇸Ignacio Gil Gomez | 1:13:40+0:21 |
| #49 | #17 | 🇪🇸Javier Aitor De Cepeda Hernández, 🇪🇸Tamara Ruiz Serrano | 1:13:44+0:04 |
| #50 | #21 | 🇪🇸Fernando Lopez Herrero, 🇪🇸Marta Pérez Litran | 1:13:45+0:01 |